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Magnesium chloride is safe as a food additive when used in accordance with regulations. Its safety depends on qualified product quality, dosage, application and consumer groups, as detailed below:
food grade magnesium chloride mainly serves three purposes: protein coagulation, texture stabilization and quality adjustment. In China, it is best known as bittern used for making tofu.
1. Protein Coagulant (Primary Use)
o Aggregates and coagulates soy protein in soymilk to form tofu and dried tofu
o Produces firm, chewy northern tofu with rich soybean flavor
o Used in tofu, dried tofu, tofu skin, fried tofu and other soy products
2. Stabilizer, Thickener and Texture Improver
o Maintains food shape and prevents collapse
o Used in:
§ Flour products (noodles, dumpling wrappers): enhances gluten strength and cooking resistance
§ Canned and pickled foods: stabilizes structure and improves taste
§ Jelly and pudding: assists gel formation
3. Mineral Fortification and Flavor Adjustment
o Supplies magnesium ions as a nutritional fortifier, e.g., in mineral water
o Mildly adjusts saltiness and umami to improve overall flavor
4. Other Auxiliary Functions
o Aquatic and meat products: retains moisture, tenderizes and improves elasticity
o Some beverages and condiments: regulates acidity and stabilizes the system
· Legal Additive: Magnesium chloride (CNS 18.003, INS 511) is a legally recognized food additive in China and globally, mainly used as a coagulant, stabilizer and flavor enhancer.
· Authoritative Safety Certifications
o JECFA (FAO/WHO): no acceptable daily intake (ADI) required
o EFSA (EU): confirmed safe at normal usage levels
o China GB 2760-2024: permitted in soy products, compound seasonings, flour products, etc.

In line with Chinese national standards (e.g., GB 25584-2010 National Food Safety Standard Food Additive Magnesium Chloride), strict dosage limits apply:
· Soy products: optimal dosage 0.20% to improve yield and quality safely
· Adult daily magnesium intake: 300–400 mg (≈3–4 g of magnesium chloride hexahydrate), rarely exceeded in normal diets
There are major differences in purity and impurity control:
Item | food grade magnesium chloride (GB 25584) | Industrial-Grade Magnesium Chloride |
Heavy metals (Pb/As) | Strictly limited (Pb≤1mg/kg, As≤0.5mg/kg) | No strict limits |
Impurities | Sulfates, ammonium salts strictly removed | High impurities |
Safety | Edible | Toxic, contains heavy metal impurities |
Consequence | Compliant and safe | Illegal addition, may cause poisoning |
·food grade magnesium chloride
o Source & standard: made from bischofite or brine, conforming to GB 2760 and GB 25584-2010, labeled “food additive” with production license number
o Applications: tofu, jelly, beverages, bread, etc., as coagulant, thickener or stabilizer
· Industrial-Grade Magnesium Chloride
o Risks: may contain heavy metals (lead, arsenic) causing gastrointestinal injury or renal damage
o Prohibition: strictly forbidden in food processing; distinguishable by labeling and sourcing
Poisoning only occurs with large oral intake:
· Acute effects: nausea, vomiting, diarrhea, stomach pain
· Hypermagnesemia: muscle weakness, diminished reflexes
· Renal burden: caution advised for people with kidney insufficiency